Exercise 2 solution Rule (PH article): a difference of one pH unit is a tenfold difference in hydrogen ion concentration. The lower pH has the higher concentration. (a) pH 1 versus pH 4: difference = 3 units, so the factor is 10^3 = 1000. The pH 1 sample has 1000 times the hydrogen-ion concentration. Check with concentrations: pH 1 is 1 x 10^-1 mol/L, pH 4 is 1 x 10^-4 mol/L; 10^-1 / 10^-4 = 1000. (b) pH 3 versus pH 5: difference = 2 units, so the factor is 10^2 = 100. The pH 3 sample (the vinegar value in the data given) has 100 times the hydrogen-ion concentration of the pH 5 sample (the black coffee value). (c) pH 3 to pH 6 is 3 units, so the concentration changes by a factor of 1000 (10^-3 mol/L falls to 10^-6 mol/L). It does not "halve": the pH scale is logarithmic, so equal steps of pH are equal factors, not equal amounts. Note: the arithmetic was run in Python (check, my own calculation).