Exercise 1 solution Start: N2 + H2 -> NH3 Step 1, count: left N = 2, H = 2; right N = 1, H = 3. Not balanced. Step 2, fix nitrogen with 2 NH3: N2 + H2 -> 2NH3. Left N = 2, H = 2; right N = 2, H = 6. Step 3, fix hydrogen with 3 H2: N2 + 3H2 -> 2NH3. Left N = 2, H = 6; right N = 2, H = 6. Atom-count table (counts run in Python for the final equation): before (N2 + H2 -> NH3) after (N2 + 3H2 -> 2NH3) N left/right 2 / 1 2 / 2 H left/right 2 / 3 6 / 6 Changing NH3 to NH2 would be changing a subscript. That makes a different substance (a different molecular formula, Chapter 5), so it is no longer the ammonia you meant. Only coefficients may be changed to balance. Note: that the product is ammonia, NH3, is given in the exercise; the balancing is the point. Nothing here comes from a page beyond the balancing rule of the Chemical equation article: each side must have the same number of atoms of each element (check, general knowledge for the substances).