Exercise 3 solution Guide (Chemical polarity article): difference below 0.5 nonpolar; roughly 0.5 to 2.0 polar; above 2.0 ionic. The Electronegativity article itself gives no cut-offs, so this is a rough guide. Differences (run in Python, larger value minus smaller): N-H: 3.04 - 2.20 = 0.84 -> between 0.5 and 2.0: polar H-F: 3.98 - 2.20 = 1.78 -> between 0.5 and 2.0: polar (the largest of the three) C-O: 3.44 - 2.55 = 0.89 -> between 0.5 and 2.0: polar None of the three is below 0.5 or above 2.0. In each polar bond the more electronegative atom (N, F, O) is at the negative end of the dipole, as the Electronegativity article says. Why a molecule with polar bonds can be nonpolar: the Chemical polarity article says the C=O bonds in carbon dioxide are polar, but "the geometry of CO2 is linear so that the two bond dipole moments cancel". The two bonds pull in opposite directions by equal amounts, so there is no net dipole. Methane works the same way through its symmetric tetrahedral arrangement. Water is the contrast: its bent shape means the two O-H dipoles do not cancel, so water is polar. Not covered by the pages: why the numbers behave this way (check, a deeper topic).